魏学红
山西大学教授博士,教授。1993年毕业于中国科学院兰州化学物理研究所获博士学位,同年到山西大学化学化工学院工作。2001.11-2003.12月分别在英国皇家学会和德国巴斯夫公司的资助下师从国际著名金属有机化学家M.F.Lappert教授、英国皇家院士进行了为期两年的博士后研究工作学进行合作研究。近五年来在Organometallics、Dalton Transactions、Journal of Materials Chemistry 等杂志上发表论文60余篇,已申请中国发明专利7项,授权4项。
研究兴趣
有机化学;金属有机化学;精细化学品化学;绿色化学
or ButCN and PhCN”, J. Organomet. Chem., 2004, 689, 1342-1349.
近期代表性发表论文
1. “The First Heterotrimetallic Salts: Synthesis, Structures and Superbase Reactivity of the Crystalline tert-Butoxides [Li4Na2K2(OtBu)8(m-L)]n [L = h6: h6-C6H6 (1), N,N’-TMEDA) (2)]”, Angew. Chem. Int. Ed. 2008, in press.
2. “Syntheses, structures and reactions of a series of β-ketiminatoyttrium compounds”, Dalton Trans., 2008, 1073-1080.
3. “Synthesis, characterization of a novel zinc diamine-bisphenolate complex and its application as an initiator for ring-opening polymerization of rac –lactide” Inorg. Chem. Commun., 2008, in press.
4. “Synthesis and structures of some sterically hindered zinc complexes containing 6-membered ZnNCCCN and ZnOCCCN rings”, J. Organomet. Chem., 2008, in press.
5. “Synthesis, structure and catalytic properties of a novel zirconium guanidinato complex [Zr{ArNC(NMe2)N(SiMe3)}(m2- Cl)Cl2]2 [ Ar = 2,6- iPr2- C6H3]”, J. Organomet. Chem., 2007,692, 5195-5202.
6. Synthesis and structures of some heterometallic [(Li, Y)2, (M3, Ce) (M= Lior Na), (Li, Zr2) and (Li, Zr)4] oligomeric diamides derived from 1,2-bis(neopentylamino)benzene”, Dalton Trans., 2006, 2991–2997.
7. “Synthesis and structures of some bimetallic (Li/Ca, Li/Zn, Li/Li) diamidesderived from 1,2-bis(neopentylamino)benzene and ofLi2[{N(SiMe2NPri2)}2C6H4-1,2](thf)3” , Dalton Trans., 2006, 1181–1187.
8. “b-Diketiminates of Some Main Group Elements: New Structural Motifs”, Modern Aspects of Main Group Chemistry, 2005, 192-207, Publisher: American Chemical Society, Washington, DC.
9. “Synthesis and structures of the chelating diamido zirconium and hafnium compounds”, Appl. Organomet. Chem., 2005, 19, 1010-1014.
10. “b-diketiminates of some main group elements: New structural motifs”, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 227: U1433 Part 1 2004, Publisher: AMER CHEMICAL SOC, WASHINGTON, ISSN: 0065-7727.
11. “Lanthanide metal amides revisited; the use of the 2,2,6,6-tetramethylpiperidinato (TMP) ligand”, J. Mater. Chem., 2004, 14, 3266 - 3273.
12. “Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium b-diketiminates”, Dalton Trans., 2004, 1567-1577.
13. “Synthesis and structures of four crystalline lithium b-diketiminates derived from [Li{CH(SiMe3)(SiMe2OMe)}]8 and PhCN or ButCN and PhCN”, J. Organomet. Chem., 2004, 689, 1342-1349.
14. “Syntheses and Structures of Alkali Metal Silylmethyls and Derived Azaallyls and b-Diketiminates”, ALKCHEM-3, Third International Conference on the Chemistry of the Alkali and Alkaline Earth Metals, P. 60, 28. 09-02.10. 2003, Würzburg, Germany.
15. “Some Unusual Alkai Metal or Magnesium Silyl-substituted Complexes: Steric and Electronic Effects and Rearrangements”, ALKCHEM-3, Third International Conference on the Chemistry of the Alkali and Alkaline Earth Metals, P. 27, 28. 09-02.10. 2003, Würzburg, Germany.
16. “Synthesis and structures of crystalline lithium 1-azaallyls and a 1,3-diazaallyl derived from Li{CH(SiMe3)(SiMe3-n(OMe)n)} (n = 1 or 2) and Li{CH(SiMe2OMe)2} and RCN (R = But, Ph, 2,5-Me2C6H3, or Ad)”, J. Organomet. Chem., 2003, 683, 83-91
17. “Synthesis and Structures of Crystalline Li, Na, K, and Mg Silylmethyls Derived from the Ligands [CH(SiMe3){ SiMe3-n(OMe)n}]- (n = 1 or 2), [CH(SiMe2OMe)2]-, and [CH(SiMe3)(SiMe2Ph)]-”, Organometallics, 2003, 23, 2505-2516.
18. “STUDIES IN 1-AZAALLYLMETAL CHEMISTRY”, Allyl Symposium, ACS Meeting, 18 –19th August 2002, Boston, USA.
19. “SYNTHESIS, STRUCTURES AND REACTIONS OF METAL COMPOUNDS OF A NOVEL b-DIKETIMINATO LIGAND”, 20th International Conference on Organometallic Chemistry, Corfu, Greece July, 2002.
20. “STUDIES IN 1-AZAALLYLMETAL CHEMISTRY”, Allyl Symposium, ACS Meeting, 18 –19th August 2002, Boston, USA.
21. “Synthesis and structures of novel chiral lithium amidinates and mono-and di-lithium(1R,2R)-(-)-1,2-(NHSiMe3)2C6H10”, J. Chem. Soc., Dalton Trans., 2002, 1401-1405.
22. “Addition reactions of bis(trimethylsilyl)methyl- and 1-azzallyl-lithium with cyanoamines into triazines or b-diketiminatolithium compounds”, J. Organomet. Chem., 2002, 655, 89-95.