尹双凤

籍 贯：

湖南邵东

工作单位

湖南大学化学化工学院

职 称：

教授，博士生导师

学术兼职：

湖南省催化与绿色化学专业委员会副主任，湖南省化学化工学会常务理事，湖南省石油学会理事，中国化学会会员，日本化学会会员

所属学科：

应用化学、化学工艺、工业催化

研究方向：

纳米催化材料、二氧化碳的资源化利用、环境催化新技术、低碳烃资源催化转化与利用、含铋新型材料。

主要学习与工作经历：

1992.9-1996.7，北京化工大学精细化工专业，学士。

1996.9-1999.3，中石化石油化工研究院有机化工专业，硕士。

1999.5-2003.7，清华大学物理化学专业，博士。

2002.12-2004.6，在香港浸会大学与区泽棠、王文成教授进行合作，分别从事氨分解制氢的高效催化剂和染料敏化太阳能电池的研究工作。

2004.4-2006.6，获日本学术振兴会（JSPS）资助，与日本综合产业技术研究所Shimada高级研究员合作探讨新型有机铋化合物的合成及其在二氧化碳固定方面的应用。

2008.6-2008.8，作为高级访问学者在香港浸会大学与《Applied Catalysis A》副主编区泽棠教授进行合作。

2009.4-2009.5，作为高级访问学者在日本综合产业技术研究所同韩立彪高级研究员开展有机磷方面的研究工作。

2004年至今在湖南大学工作，2006年晋升为教授，2007年遴选为博士生导师。

研究工作与成果介绍

研究工作涉及CO2吸收与资源化、催化新材料、新能源、绿色化工等领域。设计开发了系列新型高效催化剂和CO2吸收剂，部分研究成果具有很好的工业应用前景，并已经与企业开展放大实验研究；已共计申请专利30项（6项授权）；发表研究论文80余篇，其中Angew Chem Int Ed、Chem Commun、Chem Eur J、Green Chem、Adv Syn Catal、J Catal、Appl Catal B等SCI期刊收录近45篇，EI 收录20篇；论文被Chem Rev、J Am Chem Soc等国际刊物引用频次达400余次。获教育部高校自然科学奖二等奖10余项。

近期代表性论文(2008-2010,按照时间先后顺序)

[1] Qiu RH, Qiu YM,Yin SF*, Song XX, Meng ZG, Xu XH, Zhang XW, Luo SL, Au CT, Wong WY.Facile separation catalyst system: direct diastereoselective synthesis of (E)-α,β-unsaturated ketones catalyzed by an air-stable Lewis acidic/basic bifunctional organobismuth complex in ionic liquids,Green Chemistry, 2010, 12: 1767-1771.

[2] Zhou YB,Yin SF, Gao YX, Zhao YF, Goto M, Han LB*.Selective P-P and P-O-P bond formations via copper-catalyzed aerobic oxidative dehydrogenative couplings of H-phosphonates,Angewandte Chemie-International Edition,2010, 49: 6852 –6855.

[3] Qiu RH, Qiu YM,Yin SF*, Xu XH, Luo SL, Au CT, Wong WY, Shimada S.Highly efficient and selective synthesis of (E)-α,β-unsaturated ketones by crossed-condensation of ketones and aldehydes catalyzed by an air-stable cationic organobismuth perfluorooctanesulfonate,Advanced Synthesis & Catalysis, 2010, 352: 153-162.

[4] Dai WL, Chen L,Yin SF*, Li WH, Zhang YY, Luo SL, Au CT.High-efficiency synthesis of cyclic carbonates from epoxides and CO2over hydroxyl ionic liquid catalyst grafted onto cross-linked polymer,Catalysis Letters, 2010, 137(1-2): 74-80.

[5] Xia J, Qiu RH,Yin SF*, Zhang XW, Luo SL, Au CT, Xia K, Wong WY.Synthesis and structure of an air-stable organoantimony complex and its use as a catalyst for direct diastereoselective Mannich reactions in water,Journal of Organometallic Chemistry, 2010, 695: 1487–1492.

[6] Dai WL,Yin SF*, Guo R, Luo SL, Du X, Au CT.Synthesis of propylene carbonate from carbon dioxide and propylene oxide using Zn-Mg-Al composite oxide as high-efficiency catalyst,Catalysis Letters, 2010, 136(1): 35-44.

[7] Zhang XW, Qiu RH, Tan NY,Yin SF*, Xia J, Luo SL, Au CT.Air-stable hypervalent organobismuth (III) tetrafluoroborate as effective and reusable catalyst for the allylation of aldehyde with tetraallyltin,Tetrahedron Letters, 2010, 51(1): 153–156.

[8] Qiu RH, Zhang GP, Ren XF, Xu XH, Yang RH, Luo SL,Yin SF*.Air-stable titanocene bis(perfluorooctanesulfonate) as a new catalyst for acylation of alcohols, phenols, thiols, and amines under solvent-free condition,Journal of Organometallic Chemistry, 2010, 695: 1182–1188.

[9] Dai WL, Chen L,Yin SF*, Luo SL, Au CT.3-(2-hydroxyl-ethyl)-1-propylimidazolium bromide immobilized on SBA-15 as efficient catalyst for the synthesis of cyclic carbonates via the coupling of carbon dioxide with epoxides,Catalysis Letters, 2010, 135: 295-304.

[10] Qiu RH,Yin SF*, Zhang XW, Xia J, Xu XH, Luo SL.Synthesis and structure of air-stable cationic organobismuth perchlorate complex and its use as a highly efficient catalyst for direct diastereoselective Mannich reaction in water,Chemical Communications, 2009, (31): 4759–4761.

[11] Qiu RH, Zhang GP, Zhu YY, Xu XH, Shao LL, Li YH, An DL,Yin SF*.The synthesis and structure of extremely air-stable binuclear hafnocene perfluorooctanesulfonate complex and its use as a Lewis acid catalyst in esterification, Friedel-Crafts acylation, Mukaiyama-Aldol reaction, and allylation of aldehydes,Chemistry - A European Journal, 2009, 15(26): 6488-6454.

[12] Qiu RH, Xu XH, Li YH, Zhang GP, Shao LL, An DL,Yin SF.Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin.Chemical Communications, 2009, (13): 1679-1681.

[13]Yin SF, Shimada S.Synthesis and structure of bismuth compounds bearing a sulfur-bridged bis(phenolato) ligand and their catalytic application to solvent-free synthesis of propylene carbonate from CO2and propylene oxide,Chemical Communications, 2009, (9): 1136 - 1138.

[14] Wu SS, Cao HQ,Yin SF*, Zhang XR, Chernow V.Biomineralization and superhydrophobicity of BaCO3complex nanostrucutre,Inorganic Chemistry, 2009, 48(21), 10326-10329.

[15] Wu SS, Cao HQ,Yin SF*, Liu XW, Zhang XR.Amino acid-assisted hydrothermal synthesis and photocatalysis of SnO2nanocrystals.Journal of Physical Chemistry C, 2009, 113(41): 17893–17898.

[16] Dai WL, Luo SL,Yin SF*, Au CT.The direct transformation of carbon dioxide to organic carbonates over heterogeneous catalysts,Applied Catalysis A, 2009, 366(1): 2-12.

[17] Tao L, Chen L,Yin SF*, Luo SL, Ren YQ, Li WS, Zhou XP, Au CT.Catalytic conversion of CH3Br to aromatics over PbO-modified HZSM-5,Applied Catalysis A, 2009, 367(1-2): 99–107.

[18] Qiu RH, Zhu YY, Xu XH, Li YL, Shao LL, Ren XF, Cai XT, An DL,Yin SF*.Zirconocene bis(perfluorooctanesulfonate)s-catalyzed acylation of alcohols, phenols, thiols, and amines under solvent-free conditions,Catalysis Communications, 2009, 10(14): 1889–1892.

[19] Zhang XW,Yin SF*, Qiu RH, Xia J, Dai WL, Luo SL, Yu ZY, Au CT, Wong WY.Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water,Journal of Organometallic Chemistry, 2009, 694(22): 3559–3564.

[20] Zhang XW, Xia J, Yan HW, Luo SL,Yin SF*, Au CT, Wong WY.Synthesis, structure, and in vitro antiproliferative activity of cyclic hypervalent organobismuth(III) chlorides and their derivatives triphenylgermylpropionates,Journal of Organometallic Chemistry, 2009, 694 (18): 3019–3026.

[21]Yin SF, Maruyama J, Yamashita T, Shimada S.Efficient fixation of carbon dioxide by hypervalent organobismuth oxide, hydroxide, and methoxide,Angewandte Chemie-International Edition,2008, 47(35): 6590-6593. (hot paper)

[22] Wu SS, Zhang XW, Dai WL,Yin SF*, Li WS, Ren YQ, Au CT. ZnBr2-Ph4PI as highly efficient catalyst for cyclic carbonates synthesis from terminal epoxides and carbon dioxide,Applied Catalysis A,2008, 341(1-2): 106–111.

[23] Wu SS, Dai WL,Yin SF*, Li WS, Au CT.Bismuth subnitrate as an efficient heterogeneous catalyst for acetalization and ketalization of carbonyl compounds with diols，Catalysis Letters, 2008, 124:127-132.